ADSORPTION OF DIRECT BLACK 22 FROM AQUEOUS SOLUTION  USING Mg/Al LDH- ZEOLITE

Nguyễn Thế Duyến; Văn Hữu Tập; Đỗ Thủy Tiên; Hoàng Trung Kiên; Nguyễn Đình Vinh; Nguyễn Văn Quang

doi:10.34238/tnu-jst.4715

ADSORPTION OF DIRECT BLACK 22 FROM AQUEOUS SOLUTION USING Mg/Al LDH- ZEOLITE

About this article

Received: 30/06/21 Revised: 27/08/21 Published: 27/08/21

Authors

1. Nguyen The Duyen, Hanoi Pedagogical University 2
2. Van Huu Tap , TNU - University of Sciences
3. Do Thuy Tien, Hanoi Pedagogical University 2
4. Hoang Trung Kien, TNU - University of Sciences
5. Nguyen Dinh Vinh, TNU - University of Sciences
6. Nguyen Van Quang, Hanoi Pedagogical University 2

Abstract

In this study, composite materials between Mg/Al Layered Double Hydroxide and natural zeolite (Mg/Al LDH-zeolite) were synthesized by co-precipitation method to remove Direct Black 22 (DB22) in aqueous solution. The characteristics of Mg/Al LDH-zeolite were evaluated by scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDX), Fourier transform infrared spectra (FTIR) and Brunauer–Emmett–Teller (BET) surface area. The adsorption process of Mg/Al LDH-zeolite for DB22 was evaluated through batch experiments to examine various parameters, including solution pH, contact time and initial DB22 concentration. The DB22 adsorption isotherm and kinetic data on Mg/AlLDH-zeolite were analyzed. The results show that DB22 could be removed well by using Mg/Al LDH-zeolite due to its large surface area (252.65 m²/g) and functional groups. The DB22 adsorption capacities of Mg/Al LDH-zeolite reached 27.45 mg/g, at an initial DB22 concentration of 150 mg/L, pH = 4, and contact time of 120 min. The adsorption isotherms of DB22 on Mg/Al LDH-zeolite were described well by Langmuir models with high R² values (R² > 0.95). The obtained data also well matched the pseudo-second-order models with R² values ≥ 0.97. Physisorption through electrostatic attraction and pore filling as the main adsorption mechanism.

Keywords

Absorption; Direct Black 22; Layered Double Hydroxide; Mg/Al LDH-zeolite; Zeolite

Full Text:

PDF (Tiếng Việt)

References

[1] A. B. Dos Santos, F. J. Cervantes, and J. B.van Lier, “Review paper on current chnologies for decolourisation of textile wastewaters: perspectives for anaerobic biotechnology,” Bioresour. Technol., vol. 98, pp. 2369-2385, 2007.

[2] F. Gökçen and T. A. Özbelge, “Enhancement of biodegradability by continuous ozonation in acid red-151 solutions and kinetic modeling,” Chem. Eng. J., vol. 114, pp. 99-104, 2005.

[3] A. Ö. Yildirim, Ş. Gül, O. Eren, and E. Kuşvuran, “A comparative study of ozonation, homogeneous catalytic ozonation, and photocatalytic ozonation for C.I. reactive red 194 azo dye degradation,” Clean - Soil, Air, Water., vol. 39, pp. 795-805, 2011.

[4] F. P. Van der Zee and S. Villaverde, “Combined anaerobic-aerobic treatment of azo dyes - a short review of bioreactor studie,” Water Res., vol. 39, pp. 1425-1440, 2005.

[5] F. Fahmi, C. Z. A. Abidin, and N. R. Rahmat, “Multi-stage ozonation and biological treatment for removal of azo dye industrial effluen,” Int. J. Environ. Sci. Dev., vol. 1, pp. 193-198, 2013.

[6] S. P. Ghuge and A. K. Saroha, “Catalytic ozonation of dye industry effluent using mesoporous bimetallic Ru-Cu/SBA-15 catalyst,” Process Saf. Environ. Prot., vol. 118, pp. 125-132, 2018.

[7] S. Bashir, M. Shaaban, Q. Hussain, S. Mehmood, J. Zhu, Q. Fu, O. Aziz, and H. Hu, “Influence of organic and inorganic passivators on Cd and Pb stabilization and microbial biomass in a contaminated paddy soil,” Soils Sediments, vol. 18, pp. 2948-2959, 2018.

[8] Y. Yuan, X. Zhang, Y. Lei, Y. Jiang, Z. Xu, S. Zhang, J. Gao, and S. Zhao, “Nitrogen removal by modified zeolites coated with Zn-layered double hydroxides (Zn-LDHs) prepared at different molar ratios,” J. Taiwan Inst. Chem. Eng., vol. 87, pp. 73-82, 2018.

[9] V. M. Dang, H. T. Van, D. V. Nguyen, T. M. H. Duong, T. B. H. Nguyen, T. T. Nguyen, T. N. H. Tran, T. K. Hoang, T. P. Tran, L. H. Nguyen, and M. N. Chu, “Enhancement of exchangeable Cd and Pb immobilization in contaminated soil using Mg/Al LDH-zeolite as an effective adsorbent,” RSC Advances, vol. 11, no. 28, pp. 17007-17019, 2021.

[10] M. Kosmulski, “The pH dependent surface charging and points of zero charge. VII. Update,” Adv. Colloid Interface Sci., vol. 251, pp. 115-138, 2018.

[11] A. Dinçer, M. Sevildik, and T. Aydemir, “Optimization, isotherm and kinetics studies of the adsorption of azo dyes on eggshell membrane,” Int. J. Chem. Technol., vol. 3, no. 1, pp. 52-60, 2019.

[12] V. H. Nguyen, H. T. Van, V. Q. Nguyen, X. V. Dam, L. P. Hoang, and L. T. Ha, “Magnetic Fe₃O₄ Nanoparticle Biochar Derived from Pomelo Peel for Reactive Red 21 Adsorption from Aqueous Solution,” Journal of Chemistry, vol. 2020, pp. 1-12, 2020.

[13] G. D. Degermenci, N. De˘ germenci, V. Ayvao ˘ glu, E. Durmaz, ˘D. Çakır, and E. Akan, “Adsorption of reactive dyes on lignocellulosic waste; characterization, equilibrium, kinetic and thermodynamic studies,” J. Cleaner Production, vol. 225, pp. 1220-1229, 2019.

[14] Y. S. Ho and G. McKay, “A Comparison of chemisorption kinetic models applied to pollutant removal on various sorbents,” Process Saf. Environ. Prot., vol. 76, no. 4, pp. 332-340, 1998.

[15] Y. S. Ho and C. C. Wang, “Pseudo-isotherms for the sorption of cadmium ion onto tree fern,” Process Biochem., vol. 39, no. 6, pp. 761-765, 2004.

[16] J. R. S. Carvalho, F. M. Amaral, L. Florencio, M. T. Kato, T. P. Delforno, and S. Gavazza, “Microaerated UASB reactor treating textile wastewater: The core microbiome and removal of azo dye Direct Black 22,” Chemosphere, vol. 242, 2020, Art. no. 125157.

[17] N. T. Hien et al., “Heterogeneous catalyst ozonation of Direct Black 22 from aqueous solution in the presence of metal slags originating from industrial solid wastes,” Separation and Purification Technology, vol. 233, 2020, Art. no. 115961.

[18] M. Osmar, B. Rhayssa, H. Fernando, F. Lourdinha, T. K. Mario, and G. Savia, “Coupling intermittent micro-aeration to anaerobic digestion improves tetra-azo dye Direct Black 22 treatment in sequencing batch reactors,” Chemical Engineering Research and Design, vol. 146, pp. 369-378, 2019.

DOI: https://doi.org/10.34238/tnu-jst.4715

Refbacks

There are currently no refbacks.



Remember me