INFLUENCE OF SURFACE MODIFICATION ON ROUGHNESS AND WETTABILITY OF TITANIUM FOR POTENTIAL APPLICATIONS IN BIOMEDICINE | Trang | TNU Journal of Science and Technology

INFLUENCE OF SURFACE MODIFICATION ON ROUGHNESS AND WETTABILITY OF TITANIUM FOR POTENTIAL APPLICATIONS IN BIOMEDICINE

About this article

Received: 03/11/24                Revised: 26/11/24                Published: 26/11/24

Authors

1. Pham Hong Trang, Hanoi University of Science and Technology (HUST)
2. Nguyen Duc Hung, Hanoi University of Science and Technology (HUST)
3. Hoang Van Vuong, 1) Hanoi University of Science and Technology (HUST), 2) School of Materials Science and Technology, HUST
4. Cao Hong Ha, Hanoi University of Science and Technology (HUST)
5. Pham Hung Vuong Email to author, 1) Hanoi University of Science and Technology (HUST), 2) School of Materials Science and Technology, HUST

Abstract


The surface properties of titanium (Ti) play an important role in osseointegration, enhancing durability, reducing inflammation and therefore improving the application of Ti implants. This study focuses on a three-step chemical etching process using acid such as (H2O2: HCl), (HF: HNO3), and CH3COOH with controlled concentrations and processing times to modify the surface roughness and improve the wettability of Ti. Surface morphology of Ti was measured by a scanning electron microscope, surface roughness was examined by an optical microscope. The wettability of Ti was studied by a contact angle measurement. The results revealed that surface roughness of Ti increases from 1.54 µm to 10.09 µm with high uniformity, while the contact angle decreased from 68.9° to 51.8°. EDS analysis also confirmed the purity of the surface, free from contaminants. These results suggest that the current surface treatment is suitable for the requirement of Ti for potential applications  in biomedical implants.

Keywords


Surface; Titanium; Etching; Wettability; Roughness

References


[1] Y. Q. Liang, Z. D. Cui, S. L. Zhu, and X. J. Yang, "Characterization of self-organized TiO2 nanotubes on Ti–4Zr–22Nb–2Sn alloys and the application in drug delivery system," J. Mater Sci.: Mater Med., vol. 22, pp. 461-467, 2011.

[2] C. Moseke, F. Hage, E. Vorndran, and U. Gbureck, "TiO2 nanotube arrays deposited on Ti substrate by anodic, oxidation and their potential as a long-term drug delivery system for antimicrobial agents," Applied Surface Science, vol. 258, pp. 5399-5404, 2012.

[3] S. Kahar, A. Singh, V. Patel, and U. Kanetkar, "Anodizing of Ti and Ti Alloys for Different Applications: A Review," IJSRD - International Journal for Scientific Research & Development, vol. 8, no. 5, pp. 272 - 276, 2020.

[4] K. Mustafa, J. Wroblewsk, B. S. Lopez, A. Wennerberg, K. Hultenby, and K. Arvidson, "Determining optimal surface roughness of TiO2 blasted titanium by implant material for attachment proliferation and differentiation of cells derived from human mandibular alveolar bone," Clin. Oral Impl. Res., vol. 12, pp. 515-525, 2001.

[5] S. M. S. Tilebon, S. A. Emamian, H. Ramezanpour, H. Yousefi, M. Özcan, S. M. Naghib, Y. Zare, and K. E. Rhee, "Intelligent modeling and optimization of titanium surface etching for dental implant application," Sci. Rep., vol. 12, 2022, Art. no. 7184.

[6] R. Kohler, K. Sowards, and H. Medina, "Numerical model for acid-etching of titanium: Engineering surface roughness for dental implants," Journal of Manufacturing Processes, vol. 59, pp. 113-121, 2020.

[7] K.Y. Hung, Y. C. Lin, and H. P. Feng, "The Effects of Acid Etching on the Nanomorphological Surface Characteristics and Activation Energy of Titanium Medical Materials," Materials, vol. 10, 2017, Art. no. 1164.

[8] M. L. Nascimento, W. D. Mueller, A. C. Carvalho, and H. M. Tomás, "Electrochemical characterization of titanium biomaterials using the Mini-cell System," J. Mater Sci., vol. 41, pp. 3323-3327, 2006.

[9] A. Göransson, E. Jansson, P. Tengvall, and A. Wennerberg, "Bone formation after 4 weeks around blood-plasma-modified titanium implants with varying surface topographies: an in vivo study," Biomaterials, vol. 24, pp. 197-205, 2003.

[10] A. Bagno and C. D. Bello, "Surface treatments and roughness properties of Ti-based biomaterials," Journal of Materials Science: Materials in Medicine, vol. 15, pp. 935-949, 2004.

[11] X. X. Wang, S. Hayakawa, K. Tsuru, and A. Osaka, "A comparative study of in vitro apatite deposition on heat, H2O2 , and NaOH treated titanium surfaces," J. Biomed. Mater. Res., vol. 54, pp. 172-178, 2001.

[12] X. X Wang, S. Hayakawa, K. Tsuru, and A. Osaka, "Improvement of bioactivity of H2O2/TaCl5 treated titanium after subsequent heat treatments," J. Biomed. Mater. Res., vol. 52, pp.171-176, 2000.

[13] M. Bezuidenhouta, G. T. Haarb, and T. Beckerb, "The effect of HF-HNO3 chemical polishing on the surface roughness and fatigue life of laser powder bed fusion produced Ti-6Al-4V," Materials Today Communications, vol. 25, 2020, Art. no. 10139.

[14] A. Gristina, "Biomaterial-centered infection, microbial adhesion versus tissue integration," Science, vol. 237, pp. 1588-1595, 1987.

[15] Y. Oshida, A. Hashem, T. Nishihara, and M. V. Yapchulay, "Fractal dimension analysis of mandibular bones: towards a morphological compatibility of implants," Bone Mater. Eng., vol. 4, pp. 397-407, 1994.

[16] L. Ponsonnet, K. Reybier, N. Jaffrezic, V. Comte, and C. Lagneau, "Relationship between surface properties (roughness, wettability) of titanium and titanium alloys and cell behaviour," Materials Science and Engineering C, vol. 23, pp. 551-560, 2003.




DOI: https://doi.org/10.34238/tnu-jst.11468

Refbacks

  • There are currently no refbacks.
TNU Journal of Science and Technology
Rooms 408, 409 - Administration Building - Thai Nguyen University
Tan Thinh Ward - Thai Nguyen City
Phone: (+84) 208 3840 288 - E-mail: jst@tnu.edu.vn
Based on Open Journal Systems
©2018 All Rights Reserved