ONE STEP PREPARING OF WO3 NANOSHEETS USING ULTRASOUND-ASSISTED LIQUID-PHASE EXFOLIATION FOR PHOTOCATALYTIC DEGRADATION OF PARACETAMOL IN AQUEOUS SOLUTION | Trang | TNU Journal of Science and Technology

ONE STEP PREPARING OF WO3 NANOSHEETS USING ULTRASOUND-ASSISTED LIQUID-PHASE EXFOLIATION FOR PHOTOCATALYTIC DEGRADATION OF PARACETAMOL IN AQUEOUS SOLUTION

About this article

Received: 21/06/25                Revised: 06/11/25                Published: 07/11/25

Authors

1. Hoang Minh Trang, University of Science - Vietnam National University, Hanoi
2. Nguyen Manh Khai, University of Science - Vietnam National University, Hanoi
3. Nguyen Thi Mai, 1) University of Science - Vietnam National University, Hanoi 2) TNU - University of Agriculture and Forestry
4. Dang Van Thanh, 1) University of Science - Vietnam National University, Hanoi 2) TNU - University of Pharmacy and Medicine
5. Nguyen Thi Hai Yen, TNU - University of Education
6. Ngo Thi Mai Viet, TNU - University of Education
7. Tran Quoc Toan Email to author, TNU - University of Education

Abstract


In this study, we report on the one-step preparation of WO3 nanosheets from commercially available WO3 powder by ultrasound-assisted liquid-phase exfoliation and their application for photocatalytic degradation of paracetamol in water. The characteristics of WO3 nanosheets were studied by X-ray diffraction, field emission scanning electron microscopy, transmission electron microscope,UV-vis diffuse reflectance spectroscopy. The results showed that the initial WO3plates with uneven particle size, in the micron size, were converted to WO3 nanosheets with uniform size (50-100 nm) after 10 hours of exfoliating. The experimental results showed that with 200 mg of fabricated WO3 nanomaterial, at pH=3, the paracetamol decomposition efficiency (concentration 10 ppm, volume 400 mL) reached 85.22% after 180 minutes of Xenon lamp light illumination. This research result has opened up a simple method of fabricating WO3 nanosheets with great potential for application in the treatment of pollutants by photocatalytic degradation.

Keywords


Tungsten oxide; WO3 powder; WO3 nanosheets; Ultrasound; Paracetamol

References


[1] R. Mithuna, R. Tharanyalakshmi, J. Ishan, S. Shivangi, S. Divyanshu, D. Sovik, J. Ranjitha, G. Devanita, M. R. Mohammad, and D. Bhaskar, “Emergence of antibiotic resistance due to the excessive use of antibiotics in medicines and feed additives: A global scenario with emphasis on the Indian perspective,” Emerging Contaminants, vol. 10, 2024, Art. no. 100389.

[2] E. Brillas and M. P. J. Hernandez, "Removal of paracetamol (acetaminophen) by photocatalysis and photoelectrocatalysis. A critical review," Separation and Purification Technology, vol. 309, 2023, Art. no. 122982.

[3] F. Mansouri, K. Chouchene, N. Roche, and M. Ksibi, “Removal of Pharmaceuticals from Water by Adsorption and Advanced Oxidation Processes: State of the Art and Trends,” Appl. Sci, vol. 11, no. 6659, pp. 1-35, 2021.

[4] R. Ikram, H. Wafa, F. S. Ons, K. Nabila, H. Abdennaceur, and B. M. Hedi, ”Photocatalytic and biodegradation treatments of paracetamol: investigation of the in vivo toxicity,” Environmental Science and Pollution Research, vol. 28, pp. 14530-14545, 2021.

[5] M. P. Odeilson, P. T. Rosimara, D. S. B. Herick Ematne, A. G. Rosana, S. N. Ronaldo, J. Nirav, and M. B. Olivia, “Advances and Challenges in WO3 Nanostructures’ Synthesis,” Processes, vol 12, no. 11, 2024, Art. no. 2605.

[6] S. Ojo, D. O. M. Hafiz, K. Roziana, S. Oulavanh, A. Huda, P. H. Mohd, and A. K. Tonni, “WO3 – based photocatalysts: A review on synthesis, performance enhancement and photocatalytic memory for environmental applications,” Ceramics International, vol. 48, no.5, pp. 5845-5875, 2022.

[7] J. C. Murillo-Sierra, A. Hernández-Ramírez, L. Hinojosa-Reyes, and J. L. Guzmán-Mar, “A review on the development of visible light-responsive WO3-based photocatalysts for environmental applications,” Chemical Engineering Journal Advances, vol. 5, 2021, Art. no. 100070.

[8] S. M. Park and N. Chunghee, “Dye-adsorption properties of WO3 nanorods grown by citric acid assisted hydrothermal methods,” Ceramics International, vol. 43, no.18, pp. 17022-17025, 2017.

[9] R. Runce and W. Limin, “Synthesis of hierarchical hollow nest-like WO3 micro/nanostructures with enhanced visible light-driven photocatalytic activity,” Journal of Alloys and Compounds, vol. 850, 2021, Art. no. 156742.

[10] R. Prem, H. Suematsu, and R. Sarathi, “Single step synthesis of WO3 nanoparticles by wire explosion process and its photocatalytic behaviour,” Nano Express, vol. 2, 2021, Art. no. 020014.

[11] P. Dumindu and D. H. Michael, “Morphology-Controlled WO3 for the Photocatalytic Oxidation of Methane to Methanol in Mild Conditions, Methane, vol. 2, pp. 103–112, 2023.

[12] H. Yifei, P. Xuecheng, Zh. Yan, H. Liang, L. Tongyang, Zh. Qian, L. Yun, and L. Jizi, “A nanotree-like WO3 film with adjustable defect concentration and its photocatalytic activity,” Materials Science in Semiconductor Processing, vol. 127, 2021, Art. no. 105737.

[13] M. Leila, K. Mitra, and N. Alireza, ”Photocatalytic degradation of acid blue 74 by Co: WO3 nanoparticles: Kinetics and response surface methodology studies,” Heliyon, vol. 10, no. 3, 2024, Art. No. e24789.

[14] T. Takuya, “Mechanochemical synthesis of metal oxide nanoparticles,” Communications Chemistry, vol. 4, no. 143, pp. 1-11, 2021.

[15] G. Sylwia, S. Barbara, C. Jerzy, and J. Mietek, "Recent Developments in Sonochemical Synthesis of Nanoporous Materials," Molecules, vol. 28, no. 6, 2023, Art. no. 2639.

[16] O. Arutanti, T. Ogi, A. B. D. Nandiyanto, F. Iskandar, and K. Okuyama, “Controllable crystallite and particle sizes of WO3 particles prepared by a spray-pyrolysis method and their photocatalytic activity,” AIChE Journal, vol. 60, no.1, pp. 41-49, 2014.

[17] W. Li, T. Wang, D. Huang, C. Zheng, Y. Lai, X. Xiao, S. Cai, and W. Chen, “WO3·0.33H2O Hierarchical Microstructure with Efficient Photocatalytic Degradation Activity,” Catalysts, vol. 11, no. 496, pp.1-11, 2021.




DOI: https://doi.org/10.34238/tnu-jst.13100

Refbacks

  • There are currently no refbacks.
TNU Journal of Science and Technology
Rooms 408, 409 - Administration Building - Thai Nguyen University
Tan Thinh Ward - Thai Nguyen City
Phone: (+84) 208 3840 288 - E-mail: jst@tnu.edu.vn
Based on Open Journal Systems
©2018 All Rights Reserved