CHEMICAL FRACTION ANALYSIS AND ASSESSMENT OF MANGANESE IN TAILING AND ARGRICUTURAL SOILS SAMPLED IN THE LEAD AND ZINC MINE AREA AT HICH VILLAGE, DONG HY DISTRICT, THAI NGUYEN PROVINCE

Vương Trường Xuân; Đặng Văn Phát

doi:10.34238/tnu-jst.5541

CHEMICAL FRACTION ANALYSIS AND ASSESSMENT OF MANGANESE IN TAILING AND ARGRICUTURAL SOILS SAMPLED IN THE LEAD AND ZINC MINE AREA AT HICH VILLAGE, DONG HY DISTRICT, THAI NGUYEN PROVINCE

About this article

Received: 14/02/22 Revised: 25/04/22 Published: 26/04/22

Authors

1. Vuong Truong Xuan , TNU - University of Sciences
2. Dang Van Phat, Minh Ha high school – Quang Yen district – Quang Ninh province

Abstract

The chemical speciation of Manganese in tailing and agricultural soils in the mining area is crucial to access the contaminated levels of Manganese in soil samples collected in the mining zone. In the present study, the concentration of Manganese in soil samples was analyzed by using Inductively coupled plasma mass spectroscopy method. This study aslo applied the Tessier extraction procedure to determine chemical speciation of Manganese (Mn) in soil samples in lead/zinc mining area at Hich village, in Dong Hy district, Thai Nguyen province. The results showed that Mn existed primarily in residue fraction (F5) and least in the fraction of organic bonds (F4) in tailing samples. Whereas, in the agricultural soils, Manganese exists predominantly in the phases of Fe-Mn oxi-hydroxide (F3), carbonate (F2) and least in the phase of organic bonds (F4). According to geo-accumulation index values, tailing samples are severely contaminated with Mn, while the agricultural soil samples have no contamination of Mn. According to RAC values, tailing samples have a moderate contamination of Mn, whereas the agricultural soil samples are at high and extremely high risk of Mn contamination.

Keywords

Chemical fraction; Soil pollution; Polluted level Pb/Zn; Mine at Hich village; Manganese in soil

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References

[1] H. S. Lim, J. S. Lee, H. T. Chon, and M. Sager, “Heavy metal contamination and health risk assessment in the vicinity of the abandoned Songcheon Au-Ag mine in Korea,” J. Geochemical Explor., vol. 96, no. 2-3, pp. 223-230, 2008, doi: 10.1016/j.gexplo.2007.04.008.

[2] Q. Li, H. Ji, F. Qin, L. Tang, X. Guo, and J. Feng, “Sources and the distribution of heavy metals in the particle size of soil polluted by gold mining upstream of Miyun Reservoir, Beijing: implications for assessing the potential risks,” Environ. Monit. Assess., vol. 186, no. 10, pp. 6605-6626, 2014, doi: 10.1007/s10661-014-3877-4.

[3] N. Basu et al., “Integrated Assessment of Artisanal and Small-Scale Gold Mining in Ghana-Part 1: Human Health Review,” Int. J. Environ. Res. Public Health, vol. 12, no. 5, pp. 5143-5176, 2015, doi: 10.3390/ijerph120505143.

[4] C. S. e Silva, C. Moutinho, A. Ferreira da Vinha, and C. Matos, “Trace minerals in human health: iron, zinc, copper, manganese and fluorine,” Int. J. Sci. Res. Methodol., vol. 13, no. 3, pp. 57-80, 2019.

[5] P. K. Padmavathiamma and L. Y. Li, “Phytoavailability and fractionation of lead and manganese in a contaminated soil after application of three amendments,” Bioresour. Technol., vol. 101, no. 14, pp. 5667-5676, 2010, doi: 10.1016/j.biortech.2010.01.149.

[6] P. J. C. Favas, J. Pratas, M. E. P. Gomes, and V. Cala, “Selective chemical extraction of heavy metals in tailings and soils contaminated by mining activity: Environmental implications,” Journal of Geochemical Exploration, vol. 111, no. 3. pp. 160-171, 2011, doi: 10.1016/j.gexplo.2011.04.009.

[7] M. J. Mahanta and K. G. Bhattacharyya, “Total concentrations, fractionation and mobility of heavy metals in soils of urban area of Guwahati, India,” Environ. Monit. Assess., vol. 173, no. 1-4, pp. 221-240, 2011, doi: 10.1007/s10661-010-1383-x.

[8] G. Liu, L. Tao, X. Liu, J. Hou, A. Wang, and R. Li, “Heavy metal speciation and pollution of agricultural soils along Jishui River in non-ferrous metal mine area in Jiangxi Province, China,” J. Geochemical Explor., vol. 132, pp. 156-163, 2013, doi: 10.1016/j.gexplo.2013.06.017.

[9] B. T. K. Anh, D. D. Kim, T. Van Tua, N. T. Kien, and D. T. Anh, “Phytoremediation potential of indigenous plants from Thai Nguyen province, Vietnam,” J. Environ. Biol., vol. 32, no. 2, pp. 257-262, 2011.

[10] V. M. Dang et al., “Immobilization of heavy metals in contaminated soil after mining activity by using biochar and other industrial by-products: the significant role of minerals on the biochar surfaces,” Environmental Technology (United Kingdom), pp. 1-16, 2018.

[11] V. M. Dang et al., “Evaluation of fly ash, apatite and rice straw derived-biochar in varying combinations for in situ remediation of soils contaminated with multiple heavy metals,” Soil Sci. Plant Nutr., vol. 66, no. 2, pp. 379-388, 2020, doi: 10.1080/00380768.2020.1725913.

[12] T. T. A. Duong and V. H. Cao, “Studying the distribution of heavy metal in Cau river's sediment,” Journal of Analytical Sciences (in Vietnamese), vol. 20, no. 4, pp. 36-43, 2015.

[13] T. T. H. Pham and D. L. Vu, “Speciation of copper, zinc in columned sediment of Cau River Basin, Thai Nguyen Province,” Journal of Analytical Sciences (in Vietnamese), vol. 20, no. 3, pp. 152-160, 2015.

[14] S. Lu, Y. Wang, Y. Teng, and X. Yu, “Heavy metal pollution and ecological risk assessment of the paddy soils near a zinc-lead mining area in Hunan,” Environ. Monit. Assess., vol. 187, no. 10, 2015, doi: 10.1007/s10661-015-4835-5.

[15] S. Cheng, G. Liu, C. Zhou, and R. Sun, “Chemical speciation and risk assessment of cadmium in soils around a typical coal mining area of China,” Ecotoxicol. Environ. Saf., vol. 160, no. May, pp. 67-74, 2018, doi: 10.1016/j.ecoenv.2018.05.022.

[16] D. Qiao, G. Wang, X. Li, S. Wang, and Y. Zhao, “Pollution, sources and environmental risk assessment of heavy metals in the surface AMD water, sediments and surface soils around unexploited Rona Cu deposit, Tibet, China,” Chemosphere, vol. 248, p. 125988, 2020, doi: 10.1016/j.chemosphere.2020.125988.

[17] P. N. Nnabo, “Heavy Metal Distribution and Contamination in Soils around Enyigba Pb-Zn Mines District , South Eastern Nigeria,” Journal of Environment and Earth Science, vol. 5, no. 16. pp. 38-54, 2015.

[18] A. Pejman, G. Nabi Bidhendi, M. Ardestani, M. Saeedi, and A. Baghvand, “Fractionation of heavy metals in sediments and assessment of their availability risk: A case study in the northwestern of Persian Gulf,” Mar. Pollut. Bull., vol. 114, no. 2, pp. 881-887, Jan. 2017, doi: 10.1016/j.marpolbul.2016.11.021.

[19] M. Saleem, J. Iqbal, and M. H. Shah, “Geochemical speciation, anthropogenic contamination, risk assessment and source identification of selected metals in freshwater sediments - A case study from Mangla Lake, Pakistan,” Environ. Nanotechnology, Monit. Manag., vol. 4, pp. 27-36, 2015, doi: 10.1016/j.enmm.2015.02.002.

[20] S. Muhammad, M. T. Shah, and S. Khan, “Heavy metal concentrations in soil and wild plants growing around Pb-Zn sulfide terrain in the Kohistan region, northern Pakistan,” Microchem. J., vol. 99, no. 1, pp. 67-75, 2011, doi: 10.1016/j.microc.2011.03.012.

[21] M. Anju and D. K. Banerjee, “Multivariate statistical analysis of heavy metals in soils of a Pb-Zn mining area, India,” Environ. Monit. Assess., vol. 184, no. 7, pp. 4191-4206, 2012, doi: 10.1007/s10661-011-2255-8.

[22] C. Monterroso et al., “Heavy metal distribution in mine-soils and plants growing in a Pb/Zn-mining area in NW Spain,” Appl. Geochemistry, vol. 44, pp. 3-11, 2014, doi: 10.1016/j.apgeochem.2013.09.001.

[23] S. C. Obiora, A. Chukwu, and T. C. Davies, “Heavy metals and health risk assessment of arable soils and food crops around Pb-Zn mining localities in Enyigba, southeastern Nigeria,” J. African Earth Sci., vol. 116, pp. 182-189, Apr. 2016, doi: 10.1016/j.jafrearsci.2015.12.025.

[24] M. Khelfaoui et al., “Chemical and mineralogical characterization of weathering products in mine wastes, soil, and sediment from the abandoned Pb/Zn mine in Skikda, Algeria,” Environ. Earth Sci., vol. 79, no. 12, pp. 1-15, 2020, doi: 10.1007/s12665-020-09043-x.

[25] Can et al., “Characteristic of ore and minerals of Hich village Lead/Zinc mine,” Vietnam J. Earth Sci., vol. 33, no. 1, pp. 85-93, 2011, doi: 10.15625/0866-7187/33/1/281.

[26] S. K. Sundaray, B. B. Nayak, S. Lin, and D. Bhatta, “Geochemical speciation and risk assessment of heavy metals in the river estuarine sediments-A case study: Mahanadi basin, India,” Journal of Hazardous Materials, vol. 186, no. 2–3, pp. 1837-1846, 2011, doi: 10.1016/j.jhazmat.2010.12.081.

DOI: https://doi.org/10.34238/tnu-jst.5541

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