EVALUATION ON THE POTENTIAL REMOVAL OF CATION AND ANION DYES USING CTS/PECTIN COMPOSITE

Trần Nguyễn Phương Lan; Mai Thị Thu Sương; Huỳnh Quốc Khanh; Nguyễn Thanh Tỷ; Lý Kim Phụng; Nguyễn Hồng Nam

doi:10.34238/tnu-jst.7745

EVALUATION ON THE POTENTIAL REMOVAL OF CATION AND ANION DYES USING CTS/PECTIN COMPOSITE

About this article

Received: 14/04/23 Revised: 25/05/23 Published: 26/05/23

Authors

1. Tran Nguyen Phuong Lan , Can Tho University
2. Mai Thi Thu Suong, Can Tho University
3. Huynh Quoc Khanh, Can Tho University
4. Nguyen Thanh Ty, Can Tho University
5. Ly Kim Phung, Can Tho University
6. Nguyen Hong Nam, University of Science and Technology of Ha Noi - Vietnam Academy of Science and Technology

Abstract

This work aims to synthesize CTS/pectin composite and investigate the adsorption capacity on cation and anion dyes. The composite is generated at 30^oC, during 1 hour and the mass ratio of chitosan and pectin (C:P) = 1:9 (w/w). FT-IR result revealed that all characteristic peaks of each material are found in composite and a zeta potential of composite is -18.30 mV. The evaluation of potential removal for cation dye (methylene blue, MB) using 1C:9P composite showed that the adsorption efficiency and capacity are 63.54% and 6.354 mg/g, respectively, at pH 10, within 75 min, and MB concentration of 20 mg/L. The change of weight ratio between CTS and pectin (3C:7P) helps an increase of MB removal possibility, particularly the adsorption efficiency and capacity reach 91.82% and 27.8 mg/g, respectively. The MB adsorption process of pectin and CTS/pectin is well-described using Langmuir isotherm model. Besides, the maximum efficiency and adsorption capacity of methyl orange are 75.03% and 84.01 mg/g with the ratio 9C:1P, respectively. This proves the cationic and anionic dye treatment potential of CTS/pectin composite, with pectin originating from natural source.

Keywords

CTS/pectin composite; Methyl orange; Methylene blue; Organic dyes; Pomelo peel

Full Text:

PDF (Tiếng Việt)

References

[1] K. Mahmoudi, K. Hosni, N. Hamdi, and E. Srasra, “Kinetics and equilibrium studies on removal of methylene blue and methyl orange by adsorption onto activated carbon prepared from date pits-A comparative study,” Korean Journal of Chemical Engineering, vol. 32, no.2, pp.274-283, 2015.

[2] G. Crini, “Non-conventional low-cost adsorbents for dye removal: A review,” Bioresource Technology, vol. 97, no. 9, pp.1061-1085, 2006.

[3] M. Masuelli and M. Blumenberg, “Pectins: extraction, purification, characterization and applications,” BoD–Books on Demand, 2020.

[4] Y. Wu, W. Yang, C. Wang, J. Hu, and S. Fu, “Chitosan nanoparticles as a novel delivery system for ammonium glycyrrhizinate,” International journal of pharmaceutics, vol. 295, no. 1-2, pp. 235-245, 2005.

[5] K. D. Yao, J. Liu, G. X. Cheng, X. D. Lu, H. L. Tu, and J. A. L D. Silva, “Swelling behavior of pectin/chitosan complex films,” Journal of Applied Polymer Science, vol. 60, no. 2, pp. 279-283, 1996.

[6] P. D. Hoagland and N. Parris, “Chitosan/pectin laminated films,” Journal of Agricultural and Food Chemistry, vol. 44, no. 7, pp. 1915-1919, 1996.

[7] X. Zhao, X. Zhang, S. Tie, S. Hou, H. Wang, Y. Song, and M. Tan, “Facile synthesis of nano-nanocarriers from chitosan and pectin with improved stability and biocompatibility for anthocyanins delivery: An in vitro and in vivo study,” Food Hydrocolloids, vol. 109, 2020, Art. no. 106114.

[8] B. Hastuti and D. Siswanta, “The synthesis of carboxymethyl chitosan-pectin film as adsorbent for lead (II) metal,” International Journal of Chemical Engineering and Applications, vol. 4, no. 6, pp. 349-353, 2013.

[9] N. P. L. Tran, P. N. Le, T. H. Nguyen, T. M. T. Tran, H. V. T. Luong, and L. N. H. Cao, “Application of response surface method (RSM) to optimize the pectin extraction from pomelo peel,” (in Vietnamese), Vietnam Trade and Industry Review, vol. 10, pp. 92-97, 2021.

[10] V. K. Mourya, N. Inamdara, and N. A. Tiwari, “Carboxymethyl chitosan and its applications,” Advanced Materials Letters, vol. 1, no. 1, pp. 11-33, 2010.

[11] S. S. Rashidova, R. Y. Milusheva, L. N. Semenova, M. Y. Mukhamedjanova, N. L. Voropaeva, S. Vasilyeva, and I. N. Ruban, “Characteristics of interactions in the pectin–chitosan system,” Chromatographia, vol. 59, pp. 779-782, 2004.

[12] V. B. V. Maciel, C. M. Yoshida, and T. T. Franco, “Chitosan/pectin polyelectrolyte complex as a pH indicator,” Carbohydrate Polymers, vol. 132, pp. 537-545, 2015.

[13] E. V. Liakos, M. Lazaridou, G. Michailidou, I. Koumentakou, D. A. Lambropoulou, D. N. Bikiaris, and G. Z. Kyzas, “Chitosan adsorbent derivatives for pharmaceuticals removal from effluents: A review,” Macromol, vol. 1, no. 2, pp. 130-154, 2021.

[14] R. Rakhshaee and M. Panahandeh, “Stabilization of a magnetic nano-adsorbent by extracted pectin to remove methylene blue from aqueous solution: A comparative studying between two kinds of cross-likened pectin,” Journal of Hazardous Materials, vol. 189, no. 1-2, pp. 158-166, 2011.

[15] D. Kong, and L. D. Wilson, “Uptake of methylene blue from aqueous solution by pectin–chitosan binary composites,” Journal of Composites Science, vol. 4, no. 3, 2020, Art. no. 95.

[16] P. Ilgin, “High removal of methylene blue dye from aqueous solution by using a novel pectin-based hydrogel,” International Journal of Environmental Analytical Chemistry, vol. 102, no. 17, pp.1-19, 2020.

[17] A. B. Albadarin, M. N. Collins, M. Naushad, S. Shirazian, G. Walker, and C. Mangwandi, “Activated lignin-chitosan extruded blends for efficient adsorption of methylene blue,” Chemical Engineering Journal, vol. 307, pp. 264-272, 2017.

[18] R. Huang, Q. Liu, J. Huo, and B. Yang, “Adsorption of methyl orange onto protonated cross-linked chitosan,” Arabian Journal of Chemistry, vol. 10, no. 1, pp. 24-32, 2017.

[19] P. T. Phan, T. T. Nguyen, and T. D. T. Ngo, “Characterizations and methyl orange adsorption capacity of activated rice husk ash,” Can Tho University Journal of Science, vol. 42, pp. 50-57, 2016.

DOI: https://doi.org/10.34238/tnu-jst.7745

Refbacks

There are currently no refbacks.



Remember me