PREPARATION OF WS2 NANOSHEETS FOR LUBRICANT ADDITIVES | Tân | TNU Journal of Science and Technology

PREPARATION OF WS2 NANOSHEETS FOR LUBRICANT ADDITIVES

About this article

Received: 08/06/23                Revised: 23/06/23                Published: 23/06/23

Authors

1. Pham Minh Tan Email to author, TNU - University of Technology
2. Seng Ranika, TNU - University of Technology
3. Hoang Tien Dat, TNU - University of Technology
4. Nguyen Van Truong, TNU - University of Technology

Abstract


In this research, we studied and fabricated the two-dimensional nanomaterials WS2 by liquid phase exfoliation assisted by an ultrasonic process. X-ray diffraction (XRD) investigated the material structural properties. The 2H semiconductor phase of WS2 was maintained after the exfoliation process. The nanoparticle size was studied using scanning electron microscopy (SEM). The lateral dimension size of WS2 plates was dramatically reduced from dozens of micrometers to a few micrometers. The optical properties were studied by Raman scattering spectroscopy. The results indicated that the bulk WS2 counterpart was successfully exfoliated to the 3 – 12 atomic layers’ sheets. The lubricant additives with 0.15 weight % of E-WS2 were used to drill the composite plate with significant performance improvement compared to those without the nanomaterials mixing. This nanofluid show outstanding potential to be a promising candidate for the lubricant in the process of drilling different types of materials. In addition, WS2 nanosheets also play an essential role in preparing nanofluids.

Keywords


2D materials; Graphene/ WS2 composite; Mechanical engineering; Composite drilling; Nanofluid

References


[1] L. A. Kolahalam, I. V. K. Viswanath, B. S. Diwakar, B. Govindh, V. Reddy, and Y. L. N. Murthy, “Review on nanomaterials: Synthesis and applications,” Mater. Today Proc., vol. 18, pp. 2182-2190, 2019.

[2] A. Meneses-Franco, E. Soto-Bustamante, and M. Kogan-Bocian, “A Brief overview on synthesis and characterization of nanomaterials,” in Active Plasmonic Nanomaterials, Pan Stanford Publishing, 2015, p. 143.

[3] X. Zhao, X. Ma, J. Sun, D. Li, and X. Yang, “Enhanced Catalytic Activities of Surfactant-Assisted Exfoliated WS2 Nanodots for Hydrogen Evolution,” ACS Nano, vol. 10, pp. 2159-2166, 2016.

[4] N. Dong, Y. Li, Y. Feng, S. Zhang, X. Zhang, C. Chang, J. Fan, L. Zhang, and J. Wang, “Optical Limiting and Theoretical Modelling of Layered Transition Metal Dichalcogenide Nanosheets,” Sci. Rep., vol. 5, 2015, Art. no. 14646.

[5] M. Mohl, A. R. Rautio, G. A. Asres, M. Wasala, P. D. Patil, S. Talapatra, and K. Kordas, “2D Tungsten Chalcogenides: Synthesis, Properties and Applications,” Adv. Mater. Interfaces, vol. 7, 2020, Art. no. 2000002.

[6] Y. Ma, Y. Dai, M. Guo, C. Niu, J. Lu, and B. Huang, “Electronic and magnetic properties of perfect, vacancy-doped, and nonmetal adsorbed MoSe2, MoTe2 and WS2 monolayers,” Phys. Chem. Chem. Phys., vol. 13, pp. 15546-15553, 2011.

[7] D. Voiry, H. Yamaguchi, J. Li, R. Silva, D. C. B. Alves, T. Fujita, M. Chen, T. Asefa, V. B. Shenoy, G. Eda, and M. Chhowalla, “Enhanced catalytic activity in strained chemically exfoliated WS₂ nanosheets for hydrogen evolution,” Nat. Mater., vol. 12, pp. 850-855, 2013.

[8] N. Hu, X. Zhang, X. Wang, N. Wu, and S. Wang, “Study on Tribological Properties and Mechanisms of Different Morphology WS2 as Lubricant Additives,” Materials, vol. 13, 2020, Art. no. 1522.

[9] Y. C. Ean, J. H. Kim, S. G. Choi, W. Y. H. Liew, N. J. Siambun, and S. S. Kim, “The Effect of WS2 Powder Added Lubricant on Friction and Wear of Tetrahedral Amorphous Carbon Coating Films,” Journal of Friction and Wear, vol. 38, pp. 450-454, 2017.

[10] Q. D. Pham, M. D. Tran, M. T. Ngo, T. L. Tran, V. T. Dang, and V. T. Nguyen, “Improvement in the Hard Milling of AISI D2 Steel under the MQCL Condition Using Emulsion-Dispersed MoS2 Nanosheets,” Lubricants, vol. 8, 2020, Art. no. 62.

[11] T. D. Hoang, Q. H. Ngo, N. H. Chu, T. H. Mai, T. Nguyen, K. T. Ho, and D. Nguyen, “Ultrasonic assisted nano-fluid MQL in deep drilling of hard-to-cut materials,” Materials and Manufacturing Processes, vol. 37, pp. 712-721, 2022.

[12] S. Sharma, S. Bhagat, J. Singh, R. C. Singh, and S. Sharma, “Excitation-dependent photoluminescence from WS2 nanostructures synthesized via top-down approach,” J. Mater. Sci., vol. 52, pp. 11326-11336, 2017.

[13] H. Lin, J. Wang, Q. Luo, H. Peng, C. Luo, R. Qi, R. Huang, J. Travas-Sejdic, and C. G. Duan, “Rapid and highly efficient chemical exfoliation of layered MoS2 and WS2,” J. Alloys Compd., vol. 699, pp. 222-229, 2017.

[14] L. Liang and V. Meunier, “First-principles Raman spectra of MoS2, WS2 and their heterostructures,” Nanoscale, vol. 6, pp. 5394-5401, 2014.




DOI: https://doi.org/10.34238/tnu-jst.8095

Refbacks

  • There are currently no refbacks.
TNU Journal of Science and Technology
Rooms 408, 409 - Administration Building - Thai Nguyen University
Tan Thinh Ward - Thai Nguyen City
Phone: (+84) 208 3840 288 - E-mail: jst@tnu.edu.vn
Based on Open Journal Systems
©2018 All Rights Reserved