STUDY ON THE ADSORPTION OF DDE, DDD, AND DDT  FROM WASHING EXTRACTS OF CONTAMINATED  SOIL USING POLYANILINE/ RICE HUSK MATERIAL

Nguyễn Quang Hợp; Nguyễn Ngọc Khánh; Dương Quang Huấn; Nguyễn Xuân Bách

doi:10.34238/tnu-jst.12530

STUDY ON THE ADSORPTION OF DDE, DDD, AND DDT FROM WASHING EXTRACTS OF CONTAMINATED SOIL USING POLYANILINE/ RICE HUSK MATERIAL

About this article

Received: 10/04/25 Revised: 04/06/25 Published: 04/06/25

Authors

1. Nguyen Quang Hop , Hanoi Pedagogical University 2 (HPU2)
2. Nguyen Ngoc Khanh, Institute of Forensic Science - Ministry of Public Security, Vietnam
3. Duong Quang Huan, Hanoi Pedagogical University 2 (HPU2)
4. Nguyen Xuan Bach, Hanoi Pedagogical University 2 (HPU2)

Abstract

The treatment of pesticides that cause environmental pollution is an important issue that is actively being studied worldwide. In this study, a material composed of polyaniline and rice husk was synthesized through a chemical method, using different ratios of aniline to rice husk. These materials were analyzed and evaluated using FT-IR spectroscopy and SEM images. Adsorption experiments were conducted to assess the ability of the polyaniline/rice husk material to adsorb DDE, DDD, and DDT under various conditions (such as the nature of the adsorbent, adsorption time, adsorbent mass, and the concentration of the adsorbate). The results showed that the adsorption efficiency ranged from 61.0% to 73.7%. The Langmuir and Freundlich isotherm models were applied to study the adsorption process, revealing a maximum adsorption capacity (q_max) of 39.41 mg/g and a Freundlich constant (K_F) of 3.366. The findings highlight the potential application of the polyaniline/rice husk material for removing DDE, DDD, and DDT from contaminated soil washing extracts.

Keywords

Polyaniline; Rice husk; Adsorption; Pesticides; DDT compounds

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References

[1] J. Beard, “DDT and human health,” Science of The Total Environment, vol. 355, pp. 78-89, 2006.

[2] O. Faroon, P. Ruiz, D. Jones, et al., “Chapter 2. Health effects,” in Toxicological Profile for DDT, DDE and DDD, Agency for Toxic Substances and Disease Registry (US), 2022, pp. 15-255.

[3] Vietnam Prime Minister, Decision No. 1598/QD-TTg dated October 17, 2017 on national plan for implementation of Stockholm Convention on persistent organic pollutants by 2025 with orientation to 2030, 2017.

[4] N. Gaur, K. Narasimhulu, and Y. Pydisetty, “Recent advances in the bio-remediation of persistent organic pollutants and its effect on environment,” Journal of Cleaner Production, vol. 198, pp. 1602-1631, 2018.

[5] H. Xiang, N. Gao, X. Lu, et al., “Degradation of diuron by chlorination and UV/chlorine process: Degradation kinetics and the formation of disinfection by-products,” Separation and Purification Technology, vol. 202, pp. 365-372, 2018.

[6] F. Geneste, “Catalytic electrochemical pre-treatment for the degradation of persistent organic pollutants,” Current Opinion in Electrochemistry, vol. 11, pp.19-24, 2018.

[7] Q. T. Tran, Q. H. Nguyen, Q. H. Duong, et al., “Decompose plant protection drugs extracted from contaminated soil,” (in Vietnamese), Vietnam Journal of Chemistry, vol. 53, no. 5E3, pp. 99-102, 2015.

[8] United States Environmental Protection Agency, “Bioremediation using DARAMEND^® for treatment of POPs in soils and sediments,” United States Environmental Protection Agency, 2006. [Online]. Available: https://nepis.epa.gov/ [Accessed Mar. 6, 2023].

[9] L. E. Rios, “Removal of DDT from Soil using Combinations of Surfactants. MSc,” M. S. thesis, University of Waterloo, Waterloo, Ontario, Canada, 2010.

[10] Q. H. Nguyen, T. T. D. Le, T. N Phan, et al., “Studying a separation of persistent insecticide residues in soils using water extraction with additive QH1,” (in Vietnamese), Vietnam Journal of Chemistry, vol. 51, no. 6ABC, pp. 445-448, 2013.

[11] Q. H. Nguyen, Q. T. Tran, Q. H. Duong, et al., “Studying a separation of persistent insecticide residues in soils using water extraction with additive QH2,” (in Vietnamese), Vietnam Journal of Chemistry, vol. 53, no. 4E1, pp. 1-4, 2015.

[12] H. Zhang, Y. Xu, T. Kanyerere, et al., “Washing Reagents for Remediating Heavy-Metal-Contaminated Soil: A Review,” Frontiers in Earth Science, vol. 10, 2022, Art. no. 901570.

[13] G. Resmi, S. G. Thampi, and S. Chandrakaran, “Heavy metal removal from contaminated soil using soil washing techniques,” Nature Environment and Pollution Technology, vol. 22, no. 1, pp. 129-138, 2023.

[14] F. Okumu, M. Matoetoe, and O. Fatoki, “A novel polyaniline titanium oxide sawdust composite adsorbent for polychlorinated biphenyls,” Science Journal of Chemistry, vol. 1, no. 3, pp. 29-37, 2013.

[15] B. Budak, and S. Demirel, “Synthesis and characterization of PANI and PANI/nanometal oxides, photocatalytic and adsorbent applications,” Turkish Journal of Chemistry, vol. 47, pp. 346-363, 2023.

[16] A. Samadi, M. Xie, J. Li, et al., “Polyaniline-based adsorbents for aqueous pollutants removal: A review,” Chemical Engineering Journal, vol. 418, 2021, Art. no. 129425.

[17] P. R. Yaashikaa, P. S. Kumar, and S. Karishma, “Review on biopolymers and composites – Evolving material as adsorbents in removal of environmental pollutants,” Environmental Research, vol. 212, 2022, Art. no. 113114.

[18] T. H. Tran, Q. H. Nguyen, V. H. Hoang, et al., “Assessment of the Absorption Efficiency of Aqueous Cu(II), Pb(II) and Cr(VI) Ions on Modified PANi Materials with Rhodomyrtus Tomentosa Extracts,” (in Vietnamese), VNU Journal of Science: Natural Sciences and Technology, vol. 32, no. 4, pp. 299-304, 2016.

[19] T. H. Tran, A. Q. Vo, Q. H. Nguyen, et al., “Studying on the adsorption of chromium(VI) on polyaniline modified with activated tea residue,” Vietnam Journal of Chemistry, vol. 56, no. 5, pp. 559-563, 2018.

[20] T. T. Pham, T. T. T. Mai, M. Q. Bui, et al., “Synthesis of adsorbent materials based on polyaniline and agriculture waste by soaking method for removal heavy metal ions from solution,” ChemXpress, vol. 3, no. 1, pp. 1-10, 2014.

[21] T. T. Pham, T. T. T. Mai, M. Q. Bui, et al., “Nanostructured polyaniline rice husk composite as adsorption materials synthesized by different methods,” Advances in Natural Sciences, Nanoscience and Nanotechnology, vol. 5, no. 1, 2014, Art. no. 0150101.

[22] H. Hajjaoui, A. Soufi, W. Boumya, et al., “Polyaniline/nanomaterial composites for the removal of heavy metals by adsorption: A review,” Journal of Composites Science, vol. 5, no. 9, 2021, Art. no. 233.

[23] Q. H. Nguyen, T. H. Tran, Q. H. Duong, et al., “Studying synthesis of PANi/ sawdust material used for adsorption of DDT in contaminated soil extracts,” (in Vietnamese), Vietnam Journal of Chemistry, vol. 54, no. 6e1, pp. 221-225, 2016.

[24] Q. H. Nguyen and X. Q. Le, “Study on synthesis of PANi/coir material for adsorption of DDT in contaminated soil extracts,” (in Vietnamese), Vietnam Journal of Chemistry - International Edition, vol. 55 no. 5, pp. 611-615, 2017.

[25] P. Praipipat, P. Ngamsurach, and A. Sanghuayprai, “Modification of sugarcane bagasse with iron(III) oxide-hydroxide to improve its adsorption property for removing lead(II) ions,” Scientific Reports, vol. 13, 2023, Art. no. 1467.

[26] F. F. Severo, L. S. da Silva, J. Costa, et al., “Chemical and physical characterization of rice husk biochar and ashes and their iron adsorption capacity,” SN Applied Sciences, vol. 2, 2020, Art. no. 1286.

[27] W. Bai, M. Qian, Q. Li, et al., “Rice husk-based adsorbents for removing ammonia: Kinetics, thermodynamics and adsorption mechanism,” Journal of Environmental Chemical Engineering, vol. 9, 2021, Art. no. 105793.

[28] S. Yefremova, A. Kablanbekov, B. Satbaev, et al., “Rice Husk-Based Adsorbents for Removal of Metals from Aqueous Solutions,” Materials, vol. 16, no. 23, 2023, Art. no.7353.

[29] B. Satbaev, S. Yefremova, A. Zharmenov, et al., “Rice Husk Research: From Environmental Pollutant to a Promising Source of Organo-Mineral Raw Materials,” Materials, vol. 14, 2021, Art. no. 4119.

[30] R. Boussahel, H. Irinislimane, H. Djamila, et al., “Adsorption, kinetics, and equilibrium studies on removal of 4,4-DDT from aqueous solutions using low-cost adsorbents,” Chemical Engineering Communications, vol. 196, no. 12, pp. 1547-1558, 2009.

[31] H. Tian, J. Li, L. Zou, et al., “Removal of DDT from aqueous solutions using mesoporous silica materials,” Journal of Chemical Technology & Biotechnology, vol. 84, pp. 490–496, 2009.

[32] A. Rajan, S. Sreedharan, and V. Babu, “Solvent extraction and adsorption technique for the treatment of pesticide effluent,” Civil Engineering and Urban Planning: An International Journal, vol. 3, no. 2, pp. 155-165, 2016.

[33] M. R. Taha and S. Mobasser, “Adsorption of DDT and PCB by nanomaterials from residual soil,” PLoS ONE, vol. 10, no. 12, 2015, Art. no. e0144071.

[34] Y. J. Tu, G. S. Premachandra, S. A. Boyd, et al., “Synthesis and evaluation of Fe₃O₄-impregnated activated carbon for dioxin removal,” Chemosphere, vol. 263, 2021, Art. no. 128263

DOI: https://doi.org/10.34238/tnu-jst.12530

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