GLUCOSE SENSOR USING CYCLIC VOLTAMMETRIC METHOD  BASED ON NiO/ITO ELECTRODE

Serth Sedthiphonh; Trần Quốc Toàn; Nguyễn Văn Trường; Nguyễn Quốc Dũng

doi:10.34238/tnu-jst.4337

GLUCOSE SENSOR USING CYCLIC VOLTAMMETRIC METHOD BASED ON NiO/ITO ELECTRODE

About this article

Received: 14/04/21 Revised: 14/05/21 Published: 20/05/21

Authors

1. Serth Sedthiphonh, 1) TNU - University of Education 2) Luang Prabang Teacher Training College
2. Tran Quoc Toan, TNU - University of Education
3. Nguyen Van Truong, TNU - University of Technology
4. Nguyen Quoc Dung , TNU - University of Education

Abstract

Nickel oxide/Indium Tin Oxide (NiO/ITO) electrode was fabricated by electrodeposition method using the three-electrode system from 0.1 M NiSO₄ and 0.1 M H₂SO₄ electrolyte support solution to form Ni/ITO followed by oxidation in the air to convert Ni to NiO. The morphology and crystalline structure of NiO were characterized by SEM (Scanning Electron Microscope), XRD (X-Ray Diffraction), and Raman spectroscopy. The cyclic voltage method was used to investigate NiO/ITO electrode's electrochemical properties in the alkaline medium of NaOH solution and determine the glucose concentration. The conditions for Ni deposition onto ITO substrate were 0.1 M NiSO₄, electrolyte support of 0.1 M H₂SO₄ under deposition potential -1.2 V (vs. Ag/AgCl reference electrode) for 360 seconds. The cyclic voltammetry (CV) technique method to determine the concentration of glucose showed the linear range detection of 0 to 500 μM, R = 0.9885 with high sensitivity of 2088 µAcm^-2mM^-1 for positive scan and 0.5 to 13 mM, R = 0.9966 for negative scan, the detection limit of 5 μM.

Keywords

Nickel oxide; Choronoamperomety; Cyclic voltammetry; Glucose sensor; Noenzymatic

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DOI: https://doi.org/10.34238/tnu-jst.4337

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