PREPARATION OF CHITOSAN/POLY VINYL ALCOHOL HYDROGEL CROSSLINKED BY GLYOXAL TOWARDS APPLICATIONS IN THE REMOVAL OF COPPER (II) IONS FROM AQUEOUS SOLUTIONS | Thảo Nguyên | TNU Journal of Science and Technology

PREPARATION OF CHITOSAN/POLY VINYL ALCOHOL HYDROGEL CROSSLINKED BY GLYOXAL TOWARDS APPLICATIONS IN THE REMOVAL OF COPPER (II) IONS FROM AQUEOUS SOLUTIONS

About this article

Received: 06/09/22                Revised: 10/10/22                Published: 11/10/22

Authors

1. Bui Thi Thao Nguyen Email to author, Ho Chi Minh City University of Technology - Vietnam National University Ho Chi Minh
2. Nguyen Nhi Tru, Ho Chi Minh City University of Technology - Vietnam National University Ho Chi Minh
3. Ha Thi Tram Anh, Ho Chi Minh City University of Technology - Vietnam National University Ho Chi Minh
4. Nguyen Thi Quynh Giao, Ho Chi Minh City University of Technology - Vietnam National University Ho Chi Minh
5. Huynh Thi Ngoc Han, Ho Chi Minh City University of Technology - Vietnam National University Ho Chi Minh

Abstract


Recently, hydrogels have been utilized as effective adsorbents to remove heavy metal ions from aqueous solutions. In this study, the composite hydrogels based on chitosan and poly vinyl alcohol (PVA) crosslinked by glyoxal were conducted towards the application of removing copper ions from water. The specific functional groups of chitosan and PVA molecules were revealed by Infrared spectroscopy (FTIR). The swelling property of the composite was investigated and had the highest value of 850%. In addition, the ability of hydrogel to remove copper ions from aqueous solution was evaluated through the experiments supported by UV vis equipment. The Langmuir and Freundlich isotherm model could fit the data of the experiment. And the hydrogel with 10%wt glyoxal had maximum copper ion absorption with 183 mg.g-1 at pH 7.

Keywords


Composite hydrogel; Chitosan; PVA; Glyoxal; Copper ion

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References


[1] E.-R. Kenawy, E. A. Kamoun, M. S. M. Eldin, and M. A. El-Meligy, “Physically crosslinked poly(vinyl alcohol)- hydroxyethyl starch blend hydrogel membranes: Synthesis and characterization for biomedical applications,” Arabian Journal of Chemistry, vol. 7, pp. 372-380, 2014.

[2] S. J. Buwalda, K. W. Boere, P. J. Dijkstra, J. Feijen, T. Vermonden, and W. E. Hennink, “Hydrogels in a historical perspective: From simple networks to smart materials,” Journal of Controlled Release, vol. 190, pp. 254-273, 2014.

[3] S. C. Lee, I. K. Kwon, and K. Park, “Hydrogels for delivery of bioactive agents: A historical perspective,” Adv. Drug Deliv. Rev, vol. 65, pp. 17-20, 2013.

[4] A. Chetouani, M. Elkolli, M. Bounekhel, and D. Benachour, “Chitosan/oxidized pectin/PVA blend film: mechanical and biological properties,” Polym. Bull., vol. 74, pp. 4297-4310, 2017.

[5] Y. Zhang, P. C. Zhu, and D. Edgren, “Crosslinking Reaction Of Poly(Vinyl Alcohol) With Glyoxal,” Journal of Polymer Research, vol. 17, pp. 725-730, 2010.

[6] Z. Abdeen, S. G. Mohammad, and M. S. Mahmoud, “Adsorption of Mn (II) ion on polyvinyl alcohol/chitosan dry blendingfrom aqueous solution,” Environmental Nanotechnology, Monitoring &Managemen, vol. 3, pp. 1-9, 2015.

[7] E. A. Kamoun, X. Chen, M. S. M. Eldin, and E.-R. S. Kenawy, “Crosslinked poly(vinyl alcohol) hydrogels for wound dressing applications: A review of remarkably blended polymers,” Arabian Journal of Chemistry, vol. 8, pp. 1-14, 2015.

[8] T. Jamnongkan and K. Singcharoen, “Towards novel adsorbents: the ratio of PVA/chitosan blended hydrogels on the copper (II) ion adsorption,” Energy Procedia, vol. 89, pp. 299-306, 2016.

[9] E. Yan, M. Cao, J. Jiang, J. Gao, C. Jiang, X. Ba, X. Yang, and D. Zhang, “A novel adsorbent based on magnetic Fe3O4 contained polyvinyl alcohol/chitosan composite nanofibers for chromium (Ⅵ) removal,” Solid State Sciences, vol. 72, pp. 94-102, 2017.

[10] S. K. Vineeth, R. V. Gadhave, and P. T. Gadekar, “Glyoxal Cross-Linked Polyvinyl Alcohol Microcrystalline Cellulose Blend as a Wood Adhesive with Enhanced Mechanical, Thermal and Performance Properties,” Mat. Int., vol. 2, pp. 0277-0285, 2020.

[11] J. Chedly, S. Soares, A. Montembault, Y. von Boxberg, M. Veron-Ravaille, C. Mouffle, M.-N. Benassy, J. Taxi, L. David, and F. Nothiaset, “Physical chitosan micro hydrogels as scaffolds for spinal cord injury restoration and axon regeneration,” Biomaterials, vol. 138, pp. 91-107, 2017.

[12] E. A. El-Hefian, M. M. Nasef, and A. H. Yahaya, “The Preparation and Characterization of Chitosan/ Poly (Vinyl Alcohol) Blended Films,” E-Journal of Chemistry, vol. 7, pp. 1212-1219, 2010.

[13] S. J. Kim, S. J. Park, and S. I. Kim, “Swelling behavior of interpenetrating polymer network hydrogels composed of poly(vinyl alcohol) and chitosan,” Reactive & Functional Polymers, vol. 55, pp. 53–59, 2003.

[14] L. Li, Z. Wang, P. Ma, H. Bai, W. Dong, and M. Chen, “Preparation of polyvinyl alcohol/chitosan hydrogel compounded with graphene oxide to enhance the adsorption properties for Cu(II) in aqueous solution,” Journal of Polymer Research, vol. 22, pp. 150-160, 2015.

[15] Q. Song, J. Gao, Y. Lin, Z. Zhang, and Y. Xiang, “Synthesis of cross-linking chitosan-PVA composite hydrogel and adsorption of Cu(II) ions,” Water Science & Technology, vol. 81, pp. 1063–1070, 2020.




DOI: https://doi.org/10.34238/tnu-jst.6441

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