INVESTIGATE ON ELECTROCHEMICAL CHARACTERISTICS AND PROPERTIES OF ELECTRODEDE MATERIALS OF RTS-85 CELL TO ORIENTATE THE MANUFACTURE OF ELECTROCHEMICAL BATTERIES FOR EMERGENCY COMMUNICATION DEVICES | Hồ | TNU Journal of Science and Technology

INVESTIGATE ON ELECTROCHEMICAL CHARACTERISTICS AND PROPERTIES OF ELECTRODEDE MATERIALS OF RTS-85 CELL TO ORIENTATE THE MANUFACTURE OF ELECTROCHEMICAL BATTERIES FOR EMERGENCY COMMUNICATION DEVICES

About this article

Received: 15/08/23                Revised: 17/10/23                Published: 18/10/23

Authors

1. Phung Khac Nam Ho Email to author, Institute of Chemistry and Materials
2. Nguyen Van Bang, Institute of Chemistry and Materials
3. Le Trung Hieu, Institute of Chemistry and Materials
4. La Duc Duong, Institute of Chemistry and Materials
5. Nguyen Thi Hoai Phuong, Institute of Chemistry and Materials

Abstract


A zinc/mercuric oxide cell is a primary electrochemical battery with many advantages such as high specific energy, stable discharge voltage, small leakage current, and long storage life, and is applied in many fields of science and technology and field equipment. With these advantages, zinc/mercuric oxide batteries are still being produced and used in some countries around the world. In this study, the RTS-85 battery, a Russian-made mercury oxide cell, was studied to evaluate the electrode characteristics, cover material of the cell, and electrochemical properties by modern analytical methods. Research results show that the main component of the anode is HgO (85-95% by mass) combined with graphite (5-15% by mass). The negative electrode is a zinc-mercury amalgam (Zn content of 80-90%, Hg content of 10-20%). The research results are an important basis for orientating the design and manufacture of an electrochemical battery for emergency communication devices.

Keywords


Zinc amalgam mercury; Graphite; Primary battery; Mercury-zinc battery; Specific energy

References


[1] D. Linden and T. B. Reddy, Handbook Of Batteries third edition, New York: McGraw-Hill, 2002.

[2] V. V. Bessonov and E. P. Yanin, Mercury-containing devices and devices: environmental aspects of production and use, (in Rasian), M: IMGRE, 2004.

[3] D. W. Oxtoby, H. P. Gillis, and A. Campion, Principles of Modern Chemistry, 7th ed., Books/Cole, 2011.

[4] C. L. Clarke, Galvanic battery, US Patent 298175, 1884.

[5] S. Ruben, “Balanced Alkaline Dry Cells,” Transactions of The Electrochemical Society, vol. 92, no. 1, pp. 183-193, 1947.

[6] H. G. Mond and G. Freitag, “Review: The Cardiac Implantable Electronic Device Power Source: Evolution and Revolution,” Pacing and Clinical Electrophysiology, vol. 37, no. 12, pp. 1728-1745, 2014.

[7] B. Parker, “Obituary: a vindication of the zinc-mercury pacemaker battery,” Pacing and Clinical Electrophysiology, vol. 1, pp. 148-149, 1978.

[8] C. Sparkes and N. K. Lacey, “A study of mercuric oxide and zinc-air battery life in hearing aids,” The Journal of Laryngology & Otology, vol. 111, no. 9, pp. 814-819, 1997.

[9] A. Sharma, “A Bibliometric Analysis and Visualisation of Research Trends in Cardiac Pacemaker Battery,” Annals of R.S.C.B., vol. 25, no. 1, pp. 3697- 3704, 2021.

[10] A. J. Salkind and S. Ruben, “Mercury Batteries for Pacemakers and Other Implantable Devices,” in Batteries for Implantable Biomedical Devices, Springer US, 1986, pp. 261 – 274.

[11] S. A. G. Karunathilaka, N. A. Hampson, T. P. Haas, R. Leek, and T. J. Sinclair, “The Impedance of the Alkaline Zinc-Mercuric Oxide Cell. I. Behaviour and Interpretation of Impedance Spectra,” J. Appl. Electrochem., vol. 11, pp. 573-582, 1981.

[12] R. Hunter and K. J. Muylle, eds. European Community Deskbook. Environmental Law Institute, 1999, p. 75.

[13] N.V. Korovinab and A.M. Skundina, Handbook of Chemical Current Sources, (in Russian), M: MPEI, 2003.

[14] T. R. Crompton, Battery Reference Book, 3rd ed., Newnes, 2000.

[15] V. N. Damier and N. F. Rysukhin, Production of primary chemical current sources, (in Russian), M: Higher School, 1980.

[16] ICAO, Annex 6 Part II – International General Aviation - Aeroplanes, 10th Edition, 2018.

[17] V. S. Bagotsky, A. M. Skundin, Chemical current sources, (in Russian), Energoizdat, 1981.




DOI: https://doi.org/10.34238/tnu-jst.8549

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